130- Heptagon-Containing Saddle-Shaped Nanographenes: Self-Association and Complexation Studies with Polycyclic Aromatic Hydrocarbons and Fullerenes

A.H. G. David  , S. Míguez-Lago  , C. M. Cruz, J. M. Cuerva  , V. Blanco*, A. G. Campaña*

Organic Materials 2021, 3, 51–59

129- Studying the reactivity of alkyl substituted BODIPY. First enantioselective addition of BODIPY to MBH carbonates

M. Meazza, C. M. Cruz, A. M. Ortuño, J. M. Cuerva, L. Crovetto* R. Rios*

Chem. Sci., 2021, Accepted Manuscript DOI: : 10.1039/x0xx00000x

128- Heme-binding enables allosteric modulation in an ancient TIM-barrel glycosidase

G. Gamiz-Arco, L. I. Gutierrez-Rus, V. A. Risso, B. Ibarra-Molero, Y. Hoshino, D. Petrović, J. Justicia, J. Manuel Cuerva, A. Romero-Rivera, B. Seelig, J. A. Gavira, S. C. L. Kamerlin, E. A. Gaucher*, J. M. Sanchez-Ruiz*

Nat. commun., 2021, 12, 1-16

Article highlighted in the collection Structural biology, biochemistry and biophysics

127- Octagon‐embedded carbohelicene as chiral motif for CPL emission of saddle‐helix nanographenes

M. A. Medel, R. Tapia, V. Blanco, D. Miguel, S. P. Morcillo*, A. G. Campaña*

Angew. Chem. Int. Ed., 2021, DOI: 10.1002/anie.202015368

Article highlighted as Hot Paper.

126- Single‐Molecule Conductance of 1,4‐Azaborine Derivatives as Models of BN‐doped PAHs

L. Palomino-Ruiz, S. Rodríguez-González, J. G. Fallaque, I.R. Márquez, N. Agraït, C. Díaz, E. Leary, J. M. Cuerva, A. G. Campaña, F.Martín*, A. Millán*, M. T. Gonzalez*

Angew. Chem. Int. Ed., 2021, DOI: 10.1002/anie.202014194

125- Bioorthogonal Uncaging of Cytotoxic Paclitaxel through Pd Nanosheet–Hydrogel Frameworks

A. M. Pérez-López, B. Rubio-Ruiz, T. Valero, R. Contreras-Montoya, L. Álvarez de Cienfuegos, V. Sebastián, J. Santamaría, A. Unciti-Broceta*

J. Med. Chem. 2020, 63, 17, 9650–9659

124- Chimeric Drug Design with a Noncharged Carrier for Mitochondrial Delivery

C. Ripoll, P. Herrero-Foncubierta, V. Puente-Muñoz, M C. Gonzalez-Garcia, D. Miguel, S. Resa, J. M Paredes, M. J Ruedas-Rama, E. Garcia-Fernandez, M. Martin, M. Roldan, S. Rocha, H. D. Keersmaecker, J. Hofkens, J. M Cuerva, A. Orte*

Prepints, 2020, doi: 10.20944/preprints202012.0358.v1

123- Simple and non-charged long-lived fluorescent intracellular organelle trackers

P. Herrero-Foncubierta, M.C. González-García, S. Resa, J. M. Paredes, C. Ripoll, M. D Girón, R. Salto, J. M Cuerva, A. Orte*, D. Miguel*

Dyes and Pigments, 2020, 183, 108649

122- Nanografenos imperfectos: perfectos en la búsqueda de nuevas propiedades quirópticas

S. Míguez, A. G. Campaña*

An. Quím., 2020, 116, 132-145

Article featured as Cover in Anales de Química

121- "Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons"

V. G Jiménez, P. Mayorga Burrezo, V. Blanco, V. Lloveras, C. J. Gomez Garcia, T. Solomek, J. M. Cuerva, J. Veciana*, A. G. Campaña*

Chem. Commun., 2020, 56, 12813-12816

120- “ A Macrocycle Based on a Heptagon‐Containing Hexa‐peri‐hexabenzocoronene"

V. G. Jiménez, A. H. G. David, J. M. Cuerva, V. Blanco*, A. G. Campaña*.

Angew. Chem. Int. Ed., 2020, 59, 15124-15128

Article highlighted as Hot Paper.

119-” Detection by fluorescence microscopy of N-aminopeptidases in bacteria using an ICT sensor with multiphoton excitation: Usefulness for super-resolution microscopy ”

J. Valverde-Pozo, J. M Paredes, C. Salto-Giron, P. Herrero-Foncubierta, M. D Giron, D. Miguel, J. M Cuerva, J. M Alvarez-Pez, R. Salto, E. M Talavera*

Sensor Actuat B-Chem., 2020, 321, 128487

118-“ Two‐photon absorption enhancement by the inclusion of a tropone ring in distorted nanographene ribbons ”

S. Castro-Fernández, C. M. Cruz, I. F. A. Mariz, I. R. Márquez, V. G. Jiménez, L. Palomino-Ruiz, J. M. Cuerva, E. Maçôas, A. G. Campaña*.

Angew. Chem. Int. Ed., 2020, 59, 7139-7145

Article highlighted in the collection: Hot topic: Carbon, Graphite, and Graphene from Advanced Materials

Article highlighted in Chemistry Views: Distorted Nanographene Ribbons

Article featured as Inside Back Cover in Angewandte Chemie International Edition

117-“ Simple perylene diimide cyclohexane derivative with combined CPL and TPA properties ”

P. Reine, A. M Ortuño, I. FA Mariz, M. Ribagorda, J. M Cuerva, A. G Campaña, E. Maçôas*, D. Miguel*

Front. Chem., 2020, 8, 306

116- "An enantiopure propeller‐like trityl‐brominated radical: Bringing together a high racemization barrier and an efficient circularly polarized luminescent magnetic emitter"

P. Mayorga-Burrezo, V. G. Jiménez, D. Blasi, T. Parella, I. Ratera, A. G. Campaña*, J. Veciana*.

Chem. Eur. J., 2020, 26, 3776-3781.

Article highlighted in Chemistry Views

Article featured as Cover Feature in Chemistry - A European Journal

115-“ Orthogonal cell polarity imaging by multiparametric fluorescence microscopy ”

M C. Gonzalez-Garcia, T. Peña-Ruiz, P. Herrero-Foncubierta, D. Miguel, M. D Giron, R.l Salto, J. M Cuerva, A. Navarro, E. Garcia-Fernandez, A. Orte*

SENSOR ACTUAT B-CHEM, 2020, 309, 127770

114-“ Lipid analogs reveal features critical for hemolysis and diminish granadaene mediated Group B Streptococcus infection ”

B. Armistead, P. Herrero-Foncubierta, M. Coleman, P. Quach, C. Whidbey, J. Justicia, R. Tapia, R. Casares, A. Millán, A. Haidour, J. Rodriguez Granger, J. Vornhagen, V. Santana-Ufret, S. Merillat, K. Adams Waldorf, J. M. Cuerva*, L. Rajagopal*

Nat. Commun, 2020, 11, 1-12

113-“ The cyl genes reveal the biosynthetic and evolutionary origins of the group B Streptococcus hemolytic lipid, granadaene ”

B. Armistead, C. Whidbey, L. M Iyer, P. Herrero-Foncubierta, P. Quach, A. Haidour, L. Aravind, J. M. Cuerva, H. B Jaspan, L. Rajagopal*

FRONT MICROBIOL, 2020, 10, 3123

112-” Lysine as size-control additive in a bioinspired synthesis of pure superparamagnetic magnetite nanoparticles ”

R. Contreras-Montoya, Y. Jabalera, V. Blanco, J. M.Cuerva, C. Jiménez-López, L. Álvarez de Cienfuegos*

Cryst. Growth Des., 2020, 20, 533-542.

111-“ Influence of Thermally-Induced Structural Transformations over Magnetic and Luminiscence Properties of Tartrate-based Chiral Lanthanide Organic-Frameworks ”

U. Huizi-Rayo, A. Zabala-Lekuona, A. Terenzi, C. M Cruz, J. Manuel Cuerva, A. Rodríguez Diéguez, J. Ángel García, J. M Seco, J. Cepeda*

J. Mater. Chem. C, 2020,8, 8243-8256

110- “Atmospheric water triggers supramolecular gel formation of novel low molecular weight maslinic and oleanolic triterpenic derivatives”

K. Vega-Granados, G. Belén Ramírez-Rodríguez, R.l Contreras-Montoya, F. J Ramírez, L. Palomo, A. Parra, J. M Delgado-López, M. T Lopez-Lopez, L. Álvarez de Cienfuegos*

Mat. Chem. Front., 2019, 3, 2637-2646

109-“ Subtle chemical modification for enrichment of Fmoc-amino acid at a phospholipid interface ”

P. G Argudo, R. Contreras-Montoya, L. Álvarez de Cienfuegos, M. T Martín-Romero, L. Camacho, J. J. Giner-Casares*

RSC Advances, 2019, 64, 37188-37194

108-” Radical‐promoted C‐C bond cleavage: a deconstructive approach for selective functionalization. ”

Sara P. Morcillo*

Angew. Chem. Int. Ed., 2019, 58, 14044-14054.

“Top 10% most downloaded papers”

107-” Chiral double stapled o-OPEs with intense circularly polarized luminescence ”

P. Reine, A. G Campaña, L. Alvarez de Cienfuegos, V. Blanco, S. Abbate, A. J. Mota, G. Longhi*, D. Miguel*, J. M Cuerva*

Chem. Commun, 2019, 55, 10685-10688.

106-“ Catalytic and Electron Conducting Carbon Nanotube–Reinforced Lysozyme Crystals ”

R. Contreras‐Montoya, G. Escolano, S. Roy, M.T Lopez‐Lopez, J.M Delgado‐López, J. M Cuerva, J. J Díaz‐Mochón, N. Ashkenasy*, J. A Gavira*, L. Álvarez de Cienfuegos*

Adv. Funct. Mater, 2019, 29, 1807351

105-“ Extending the pool of compatible peptide hydrogels for protein crystallization .”

G. Escolano-Casado, R. Contreras-Montoya, M. Conejero-Muriel, A. Castellví, J. Juanhuix, M. T Lopez-Lopez, L. Álvarez de Cienfuegos*, J. A Gavira*

Crystals, 2019, 244

104-“ Novel Oleanolic and Maslinic Acids derivatives as a promising treatment against bacterial biofilm in nosocomial infections: An in Vitro and in Vivo study .”

E. Torrents, N. Blanco-Cabra, K. Vega-Granados, L. Moya-Andérico, M. Vukomanovic, A. Parra, L. > Álvarez de Cienfuegos*

ACS Infect. Dis., 2019, 1581-1589

103-” Direct determination of phenolic secoiridoids in olive oil by ultra-high performance liquid chromatography-triple quadruple mass spectrometry analysis ”

A. Luque-Muñoz, R. Tapia, A. Haidour, J. Justicia, J. M Cuerva*

Scientific reports., 2019, 9, 1-9.

102-” A [2] Rotaxane-Based Circularly Polarized Luminescence Switch ”

A. HG David, R. Casares, J. M Cuerva*, A. G Campaña, V. Blanco*

J. Am. Chem. Soc., 2019, 141, 18064-18074.

101-” A solvatofluorochromic silicon-substituted xanthene dye useful in bioimaging ”

L. Espinar-Barranco, P. Luque-Navarro, M. A Strnad, P. Herrero-Foncubierta, L.Crovetto, D. Miguel, M. D Giron, A. Orte, J. M Cuerva, R. Salto, J. M Alvarez-Pez*, J. M Paredes*

Dyes and Pigment., 2019, 168, 264-272.

100-” Organic free radicals as circularly polarized luminescence ”

P. Mayorga Burrezo, V. G. Jiménez, D. Blasi, I. Ratera, A. G. Campaña, J. Veciana*

Angew, Chem. Int. Ed., 2019, 58, 16282-16288.

99-” Enhanced Stability against Radiation Damage of Lysozyme Crystals Grown in Fmoc-CF Hydrogels ”

R. Contreras-Montoya, A. Castellví, G. Escolano-Casado, J. Juanhuix, M. Conejero-Muriel, M.T Lopez-Lopez, J. M Cuerva, L. Álvarez de Cienfuegos*, J. A Gavira*

Cryst. Growth Des., 2019, 19, 4229-4233.

98-” Chiral Molecular Ruby [Cr(dqp)2]3+ with Long-Lived Circularly Polarized Luminescence ”

J.-R. Jiménez, B. Doistau, C. M Cruz, C. Besnard, J. M Cuerva, A.G Campaña*, C. Piguet*

J. Am. Chem. Soc., 2019, 141, 13244-13252.

97-“” Combining Defects in a Single Nanographene: A Fully Helical Saddle Ribbon ”

C. M. Cruz, S. Castro-Fernández, E. Maçôas, A. Millán, A. G. Campaña*

Synlett, 2019, 30, 997-1002.

Article highlighted on the front cover of Synlett

96-” [2]Rotaxane End-Capping Synthesis by Click Michael-Type Addition to the Vinyl Sulfonyl Group ”

A. H. G. David, P. García-Cerezo, A. G. Campaña, F. Santoyo-González*, V. Blanco*

Chem. Eur. J., 2019, 25, 6170-6179.

95-” A Triskelion‐Shaped Saddle–Helix Hybrid Nanographene ”

C. M Cruz, I. R Márquez, S. Castro‐Fernández, J. M Cuerva, E. Maçôas*, A. G Campaña*

Angew. Chem. Int. Ed., 2019, 131, 8152-8156.

94-” Design, synthesis and photophysical studies of improved xanthene dye to detect acetate ”

J. M. Paredes*, D. Miguel, S. Resa, MdC Gonzalez-Garcia, Y. Diaz-Torres, J. Manuel Cuerva,* L. Crovetto J.*

Photochem. Photobiol. C, 2019, 371, 300-305.

93-” New thiol-sensitive Dye Application for Measuring oxidative stress in Cell Cultures ”

V. Puente-Muñoz, J. M Paredes*, S. Resa, J. Damaso Vílchez, M. Zitnan, D. Miguel, M. Dolores Girón, J. M Cuerva, R. Salto, L. Crovetto*

Scientific Reports, 2019, 9, 1659.

92-” Optically active Ag (i): o-OPE helicates using a single homochiral sulfoxide as chiral inducer ”

S. Resa, P. Reiné, L. Álvarez de Cienfuegos, S. Guisán-Ceinos, M. Ribagorda, G. Longhi, G. Mazzeo, S. Abbate, A. J Mota, D. Miguel*, J. M Cuerva*

Org. Biomol. Chem, 2019, 17, 8425-8434.

91-“ Anisotropic magnetic hydrogels: design, structure and mechanical properties ” C. Gila-Vilchez,

M.C Mañas-Torres, R. Contreras-Montoya, M. Alaminos, J. DG Duran, L. Álvarez de Cienfuegos, M. T Lopez-Lopez*

Philos T R Soc A, 2019, 377, 20182017

90-” Coupled Excited-State Dynamics in N-Substituted 2-Methoxy-9-Acridones ”

M. C. Gonzalez-Garcia, P. Herrero-Foncubierta, S. Castro, S. Resa, J. M Alvarez-Pez, D. Miguel, J. M Cuerva, E. Garcia-Fernandez, A. Orte*

Frontiers in chemistry. 2019, 7, 129.

89-“ Optimization of Amino Acid Sequence of Fmoc-Dipeptides for Interaction with Lipid Membranes ”

P. G Argudo, R. Contreras-Montoya, L. Álvarez de Cienfuegos, M. T Martín-Romero, L. Camacho, J. J Giner-Casares*

J PHYS CHEM B, 2019, 17, 3721-3730

88-““ O-H and (CO)N-H bond weakening by coordination to Fe(II) ”

S. Resa, A. Millán*, N. Fuentes, L. Crovetto, M. L. Marcos, L. Lezama, D. Choquesillo-Lazarte, V. Blanco, A. G. Campaña, D. J. Cárdenas*, J. M. Cuerva*

Dalton Trans. 2019, 48, 2179-2189.

87-““ Catalytic and electron conducting carbon nanotube-reinforced lysozyme crystals ”

R. Contreras-Montoya, G. Escolano, S. Roy, M. T. López-López, J. M. Delgado-López, J. M. Cuerva, J. J. Díaz-Mochón, N. Ashkenasy, J. A. Gavira, L. Álvarez de Cienfuegos*

Adv. Funct. Mater. 2019, 29, 1807351.

86-““ Combining defects in a single nanographene: A fully helical saddle ribbon ”

C. M. Cruz, S. Castro-Fernández, E. Maçoas, A. Millán, A. G. Campaña*

Synlett 2019, 997-1002.

2018:

85-““ OFF/ON switching of circularly polarized luminescence by oxophilic interaction of homochiral sulfoxidecontaining o-OPEs with metal cations ”

P. Reiné, A. M. Ortuño, S. Resa, L. Álvarez de Cienfuegos, V. Blanco, M. J. Ruedas-Rama, G. Mazzeo, S. Abbate, A. Lucotti, M. Tommasini, S. Guisán-Ceinos, M. Ribagorda, A. G. Campaña, A. Mota, G. Longhi, D. Miguel, J. M. Cuerva

Chem. Comm. 2018, 54, 13985-13988.

84-” Quantification of oleacein and oleuropein aglycone in olive oil using deuterated surrogates by normal-phase ultra high performance liquid chromatography with quadrupole time-of-flight mass spectrometry ”

A. Luque-Muñoz, R. Tapia, A. Haidour, J. Justicia, J. M. Cuerva*

l J. Sep. Sci. 2018, 41, 4272-4280.

83-” Circularly polarized luminescence of boronic acid-derived salicylidenehydrazone complexes containing chiral boron as stereogenic unit ”

V. G. Jiménez, F. M. F. Santos, S. Castro-Fernández, J. M. Cuerva, P. M. Gois, U. Pischel*, A. G. Campaña*

J. Org. Chem. 2018, 83, 14057-14062.

82-” Unravelling the 2D self-assembly of Fmoc-dipeptides at fluid interfaces ”

P. G. Argudo, R. Contreras-Montoya, L. Álvarez de Cienfuegos*, J. M. Cuerva, M. Cano, D. Alba-Molina, M. T. Martín-Romero, L. Camacho, J. J. Giner Casares*

Soft Matter 2018, 14, 9343-9350.

81-” Exploring potentialities and limitations of stapled o-oligo(phenyleneethynylene)s (o-OPEs) as efficient circularly polarized luminescence emitters ”

P. Reiné, J. Justicia, S. P. Morcillo, G. Mazzeo, E. García-Fernández, A. Rodríguez-Diéguez, L. Álvarez de Cienfuegos, S. Abbate, J. M. Cuerva, G. Longhi*, D. Miguel*

Chirality 2018, 30, 43-54.

80-““ A red-emitting, multidimensional sensor for the simultaneous cellular imaging of biothiols and phosphate ions ”

P. Herrero-Foncubierta, J. M. Paredes, M. D. Giron, R. Salto, J. M. Cuerva, D. Miguel, A. Orte*

Sensors 2018, 18, 161.

79-““ Baldwin-type rules for metal-controlled intramolecular migratory insertions. A computational study of Ni, Pd, and Pt case ”

B. Fiser, J. M. Cuerva*, E. Gómez-Bengoa *

Organometallics 2018, 37, 390-395.

78-““ Sulfoxide-induced homochiral folding of ortho-phenylene ethynylenes (o-OPEs) by silver(I) templating: Structure and chiroptical properties ”

S. Resa, D. Miguel, S. Guisán-Ceinos, G. Mazzeo, D. Choquesillo-Lazarte, S. Abbate, L. Crovetto, D. J. Cárdenas, M. C. Carreño, M. Ribagorda, G. Longhi, A. J. Mota, L. Álvarez de Cienfuegos*, J. M. Cuerva*

Chem. Eur. J. 2018, 24, 2653-2662.

77-““ Iron nanoparticles-based supramolecular hydrogels to originate anisotropic hybrid materials with enhanced mechanical strength ”

R. Contreras-Montoya, A. B. Bonhome-Espinosa, A. Orte, D. Miguel, J. M. Delgado-López, J. D. G. Duran, J. M. Cuerva, M. T. Lopez-Lopez, L. Álvarez de Cienfuegos*

Chem. Front. 2018, 2, 686-699.

76-““ The role of oligomeric gold-thiolate units in single-molecule junctions of thiol-anchored molecules ”

E. Leary, L. A. Zotti, D. Miguel, I. R. Márquez, L. Palomino-Ruiz, J. M. Cuerva, G. Rubio-Bollinger, M. T. González, N. Agrait*

J. Phys Chem. C 2018, 122, 3211-3218.

75-““ Aggregation-induced emission of [3]cumulenes functionalized with heptagon-containing polyphenylenes ”

V. G. Jiménez, R. Tapia, M. A. Medel, I. F. A. Mariz, T. Ribeiro, V. Blanco, J. M. Cuerva, E. Maçôas, A. G. Campaña*

Chem. Commun. 2018, 54, 3359-3362.

74-““ Enantiopure distorted ribbon-shaped nanographene combining two-photon absorption-based upconversion and circularly polarized luminescence ”

C. M. Cruz, I. R. Márquez, I. F. A. Mariz, V. Blanco, C. Sánchez-Sánchez, J. M. Sobrado, J. A. Martín-Gago, J. M. Cuerva, E. Maçôas*, A. G. Campaña*

Chem. Sci. 2018, 9, 3917-3924.

73-““ The role of oligomeric gold-thiolate units in single molecule junctions of thiol-anchored molecules ”

E. Leary, L. A. Zotti, D. Miguel, I. Rodríguez-Márquez, L. Palomino-Ruiz, J. M. Cuerva, G. Rubio-Bollinger, M. T. González, N. Agrait*

Cond. Mat. 2018, 1-9.

72-““ Iron nanoparticles-based supramolecular hydrogels to originate anisotropic hybrid materials with enhanced mechanical strength ”

R. Contreras-Montoya, A. B. Bonhome-Espinosa, A. Orte, D. Miguel, J. M. Delgado-López, J. D. G. Durán, J. M. Cuerva, M. T. López-López, L. Álvarez de Cienfuegos*

Mater. Chem. Front. 2018, 2, 686-699.

71-““ Synthesis of distorted nanographenes containing seven- and eight-membered carbocycles ”

I. R. Márquez, S. Castro-Fernández, A. Millán, A. G. Campaña*

Chem. Commun. 2018, 54, 6705-6718.

70-” Pyrene-containing ortho-oligo(phenylene)ethynylene foldamer as a ratiometric probe based on circularly polarized luminescence ”

P. Reiné, J. Justicia, S. P. Morcillo, S. Abbate, B. Vaz, M. Ribagorda, Á. Orte, L. Álvarez de Cienfuegos, G. Longhi, A. G. Campaña, D. Miguel*, J. M. Cuerva*

J. Org. Chem. 2018, 83, 4455-4463.

69-““ Undecabenzo[7]superhelicene: a helical nanographene ribbon as CPL emitter ”

C. M. Cruz, S. Castro-Fernández, E. Maçôas, J. M. Cuerva, A. G. Campaña*

Angew. Chem. Int. Ed. 2018, 57, 14782-14786.

2017:

68-“Efficient acetate sensor in biological media based on a selective Excited State Proton Transfer (ESPT) reaction”

V. Puente-Muñoz, J. M. Paredes, S. Resa, A. M. Ortuño, E. M. Talavera, D. Miguel, J. M. Cuerva, L. Crovetto

Sensors & Actuators, B: Chemical 2017, 250, 623-628.

67-“Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes”

I. R. Márquez, N. Fuentes, C. Cruz, V. Puente-Muñoz, L. Sotorrios, M. L. Marcos, D. Choquesillo-Lazarte, B. Biel, L. Crovetto, E. Gómez-Bengoa, T. M. González, R. Martín, J. M. Cuerva, A. G. Campaña

Chem. Sci. 2017, 8, 1068-1074.

66-“Synthesis of substituted γ- and δ-lactams based on titanocene(III)-catalysed radical cyclisations of trichloroacetamides”

F. Diaba, E. Gómez-Bengoa, J. M. Cuerva, J. Bonjoch, J. Justicia

RSC Adv. 2016, 6, 55360-55365.

65-“Stapled helical o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(I)-sensitivity”

S. P. Morcillo, D. Miguel, L. Álvarez de Cienfuegos, J. Justicia, S. Abbate, E. Castiglioni, C. Bour, M. Ribagorda, D. J. Cárdenas, J. M. Paredes, L. Crovetto, D. Choquesillo-Lazarte, A. J. Mota, M. C. Carreño, G. Longhi, J. M. Cuerva

Chem. Sci. 2016, 7, 5663-5670.

64-“Amide-substituted titanocenes in hydrogen-atom transfer catalysis”

Y. -Q. Zhang, V. Jakoby, K. Stainer, A. Schmer, S. Klare, M. Bauer, S. Grimme, J. M. Cuerva, A. Gansäuer

Angew. Chem. Int. Ed. 2016, 55, 1523–1526.

63-“Protein crystallization in short-peptide supramolecular hydrogels. A versatile strategy towards biotechnological composite materials”

M. Conejero-Muriel, R. Contreras-Montoya, J. J. Díaz-Mochón, L. Álvarez de Cienfuegos, J. A. Gavira

Cryst. Eng. Comm. 2015, 17, 8072–8078.

62-“Two-dimensional carbon-based conductive materials with dynamically-controlled asymmetric Dirac cones” > D. Miguel, I. R. Marquez, L. Álvarez de Cienfuegos, N. Fuentes, S. Rodríguez-Bolívar, D. J Cardenas, A. J. Mota, F. M. Gómez-Campos, J. Manuel Cuerva

Phys. Chem. Chem. Phys. 2015, 17, 31902–31910.

61-“Toward multiple conductance pathways with heterocycle-based oligo(phenyleneethynylene) derivatives”

D. Miguel, L. Álvarez de Cienfuegos, A. Martín-Lasanta, S. P. Morcillo, L. A. Zotti, E. Leary, M. Bürkle, Y. Asai, R. Jurado, D. J. Cárdenas, G. Rubio-Bollinger, N. Agraït, J. M. Cuerva, M. T. González

J. Am. Chem. Soc. 2015, 137, 13818–13826.

60-“Photophysics of a live-cell-marker, red silicon-substituted xanthene dye”

L. Crovetto, A. Orte, J. M. Paredes, S. Resa, J. Valverde, F. Castello, D. Miguel, J. M. Cuerva, E. M. Talavera, J. M. Álvarez-Pez

J. Phys. Chem. A 2015, 119, 10854-10862.

59-“New dual fluorescent probe for simultaneous biothiol and phosphate bioimaging”

S. Resa, A. Orte, D. Miguel, J. M. Paredes, V. Puente-Muñoz, R. Salto, M. D. Girón, M. J. Ruedas-Rama, J. M. Cuerva, J. M. Álvarez-Pez, L. Crovetto

Chem. Eur. J. 2015, 21, 14772-14779.

58-“Development of a new dual polarity and viscosity probe based on the foldamer concept”

D. Miguel, S. P. Morcillo, A. Martín-Lasanta, N. Fuentes, L. Martínez-Fernández, I. Corral, M. J. Ruedas-Rama, D. J. Cárdenas, L. Álvarez de Cienfuegos, A. Orte, J. M. Cuerva

Org. Lett. 2015, 17, 2844-2847.

57-“Influence of the chirality of short peptide supramolecular hydrogels in protein crystallogenesis”

M. Conejero-Muriel, J. A. Gavira, E. Pineda-Molina, A. Belsom, M. Bradley, M. Moral, J. D. García-López Durán, A. Luque González, J. J. Díaz-Mochón, R. Contreras-Montoya, A. Martínez-Peragón, J. M. Cuerva, L. Álvarez de Cienfuegos

Chem. Commun. 2015, 51, 3862-3865.

56-“Novel ortho-ope metallofoldamers: binding-induced folding promoted by nucleating Ag(I)-alkyne interactions”

A. Martín-Lasanta, L. Álvarez de Cienfuegos, A. Johnson, D. Miguel, A. J. Mota, A. Orte, M. J. Ruedas-Rama, M. Ribagorda, D. J. Cárdenas, M. C. Carreño, A. M. Echavarren, J. M. Cuerva

Chem. Sci. 2014, 5, 4582-4591.

55-“Structural versus electrical functionalization of oligo(phenylene ethynylene) diamine molecular junctions”

M. T. González, X. Zhao, D. Z. Manrique, D. Miguel, E. Leary, M. Gulcur, A. S. Batsanov, G. Rubio-Bollinger, C. J. Lambert, M. R. Bryce, N. Agraït

J. Phys. Chem. C 2014, 118, 21655–21662.

54-“Rational design of a new fluorescent ‘ON/OFF’ xanthene dye for phosphate detection in live cells”

A. Martínez-Peragón, D. Miguel, A. Orte, A. J. Mota, M. J. Ruedas-Rama, J. Justicia, J. M. Álvarez-Pez, J. M. Cuerva, L. Crovetto

Org. Biomol. Chem. 2014, 12, 6432-6439.

53-“Ti(III)-catalyzed cyclizations of ketoepoxypolyprenes: Control over the number of rings and unexpected stereoselectivities”

S. P. Morcillo, D. Miguel, S. Resa, A. Martín-Lasanta, A. Millán, D. Choquesillo-Lazarte, J. M. García-Ruiz, A. J. Mota, J. Justicia, J. M. Cuerva

J. Am. Chem. Soc. 2014, 136, 6943−6951.

52-“Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates”

I. Rodríguez-Márquez, A. Millán, A. G. Campaña, J. M. Cuerva

Org. Chem. Front. 2014, 1, 373-381.

51-“Ti/Ni-mediated inter and intramolecular conjugate addition of aryl and alkenyl halides and triflates”

I. Rodríguez-Márquez, D. Miguel, A. Millán, M. L. Marcos, L. Álvarez de Cienfuegos, A. G. Campaña, J. M. Cuerva

J. Org. Chem. 2014, 79, 1529–1541.

50-“Highly regioselective and chemoselective titanocene mediated Barbier-type allylations”

S. P. Morcillo, A. Martínez-Peragón, V. Jakoby, A. J. Mota, C. Kube, J. Justicia, J. M. Cuerva, A. Gansäuer

Chem. Commun. 2014, 50, 2211-2213.

49-“Recent applications of Cp2TiCl in natural product synthesis”

S. P. Morcillo, D. Miguel, A. G. Campaña, L. Álvarez de Cienfuegos, J. Justicia, J. M. Cuerva

Org. Chem. Front. 2014, 1, 15-33.

48-“Synthesis and photophysics of a new family of fluorescent 9-alkyl substituted xanthenones”

A. Martínez-Peragón, D. Miguel, R. Jurado, J. Justicia, J. M. Álvarez-Pez, J. M. Cuerva, L. Crovetto

Chem., Eur. J. 2014, 20, 447-455.

47-“The role of water-based hydrogen atom wires in long range electron transfer reactions in aqueous media for the Fe(II)-Fe(III) self-exchange and related systems”

A. G. Campaña, E. Buñuel, J. M. Cuerva, D. J. Cárdenas

Chem., Eur. J. 2013, 19, 16187-16191.

46-“Titanocene(III)-catalyzed 6-exo versus 7-endo cyclizations of epoxypolyprenes: Efficient control and synthesis of versatile terpenic building blocks”

J. Justicia, T. Jiménez, D. Miguel, R. Contreras-Montoya, R. Chahboun, E. Álvarez-Manzaneda, Daniel Collado-Sanz, D. J. Cárdenas, J. M. Cuerva

Chem., Eur. J. 2013, 19, 14484-14495.

45-“Dichlorobis(cyclopentadienyl)titanium”

D. Miguel, A. G. Campaña, J. Justicia, J. M. Cuerva

e-EROS Encyclopedia of Reagents for Organic Synthesis 2013, 1-12.

44-“Water control over the chemoselectivity of Ti/Ni multimetallic system: Heck- or reductive-type cyclization reactions of alkyl iodides”

A. Millán, L. Álvarez de Cienfuegos, D. Miguel, A. G. Campaña, J. M. Cuerva

Org. Lett. 2012, 14, 5984-5987.

43-“A versatile bottom-up approach to stapled p-conjugated helical scaffolds: Synthesis and chiroptical properties of cyclic o-phenylene ethynylene oligomers”

N. Fuentes, A. Martín-Lasanta, L. Álvarez de Cienfuegos, R. Robles, D. Choquesillo-Lazarte, J. M. García-Ruiz, A. J. Mota, L. Martínez-Fernández, I. Corral, D. J. Cárdenas, M. Ribagorda, M. C. Carreño, J. M. Cuerva

Angew. Chem. Int. Ed. 2012, 51, 13036-13040.

42-“Thermal-driven nanofuses based on organometallic rotors”

A. J. Mota, L. Álvarez de Cienfuegos, S. P. Morcillo, N. Fuentes, D. Miguel, S. Rodríguez-Bolívar, F. M. Gómez-Campos, D. J. Cárdenas, J. M. Cuerva

ChemPhysChem 2012, 13, 3857-3865.

41-“Clarifying the structure of granadaene: Total synthesis of related analogue [2]-granadaene and confirmation of its absolute stereochemistry”

M. Paradas, R. Jurado, A. Haidour, J. Rodríguez Granger, A. Sampedro Martínez, M. de la Rosa Fraile, R. Robles, J. Justicia, J. M. Cuerva

Bioorg. Med. Chem. 2012, 20, 6655-6661.

40-“Combining the Power of TiIII-mediated Processes for an Easy Access to Hydroxylated Polycyclic Terpenoids. Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide”

T. Jiménez, S. P. Morcillo, A. Martín-Lasanta, D. Collado-Sanz, D. J. Cárdenas, A. Gansäuer, J. Justicia, J. M. Cuerva

Chem., Eur. J. 2012, 18, 12825-12833.

39-“Model System for Cell Adhesion Mediated by Weak Carbohydrate−Carbohydrate Interactions”

B. Lorenz, L. Álvarez de Cienfuegos, M. Oelkers, E. Kriemen, C. Brand, M. Stephan, E. Sunnick, D. Yüksel, V. Kalsani, K. Kumar, D. B. Werz, A. Janshoff

J. Am. Chem. Soc. 2012, 134, 3326-3329.

38-“Ti/Ni-Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds”

A. Martínez-Peragón, Alba Millán, A. G. Campaña, I. Rodríguez-Márquez, S. Resa, D. Miguel, L. Álvarez de Cienfuegos, J. M. Cuerva

Eur. J. Org. Chem. 2012, 1499-1503.

37-“Influence of the Number of Anchoring Groups in the Electronic and Mechanical Properties of Benzene-, Anthracene- and Pentacene-Based Molecular Devices”

A. Martín-Lasanta, D. Miguel, T. García, J. A. López-Villanueva, S. Rodríguez-Bolivar, F. M. Gómez-Campos, E. Buñuel, D. J. Cárdenas, L. Álvarez de Cienfuegos, J. M. Cuerva

ChemPhysChem 2012, 13, 860-868.

36-“H2O-Activation for HAT: Correct Structures and Revised Mechanisms”

A. Gansäuer, A. Cangönül, M. Behlendorf, C. Kube, J. M. Cuerva, J. Friedrich, M. van Gastel

Angew. Chem. Int. Ed. 2012, 51, 3266–3270.

35-“on/off Electrochemical Switches Based on Quinone-Bisketals”

N. Fuentes, L. Álvarez de Cienfuegos, A. Parra, D. Choquesillo-Lazarte, J. M. García-Ruiz, M. L. Marcos, E. Buñuel, M. Ribagorda, M. C. Carreño, D. J. Cárdenas, J. M. Cuerva

Chem. Commun. 2011, 47, 1586-1588.

This article has received an special metion in the journal Chemicals&Engineering News.

34-“Titanium/Palladium-Mediated Regioselective Propargylation of Ketones Using Propargylic Carbontates as Pronucleophiles”

A. Millán, L. Álvarez de Cienfuegos, A. Martín-Lasanta, A. G. Campaña, J. M. Cuerva

Adv. Synth. Catal. 2011, 353, 73-78.

33-“Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling reactions”

A. Millán, A. G. Campaña, B. Bazdi, D. Miguel, L. Álvarez de Cienfuegos, A. M. Echavarren, J. M. Cuerva

Chem., Eur. J. 2011, 17, 3985-3994.

32-“Titanocene(III)-Promoted Barbier-type Crotilation of Carbonyl Compounds”

I. Sancho-Sanz, D. Miguel, A. Millán, R. E. Estévez, J. L. Oller-López, E. Álvarez-Manzaneda, R. Robles, J. M. Cuerva, J. Justicia

J. Org. Chem. 2011, 76, 732-735.

31-“Conductance and Application of Organic Molecule Pairs as Nanofuses”

S. Rodríguez-Bolívar, F. M. Gómez-Camposa, L. Álvarez de Cienfuegos, N. Fuentes, D. J. Cárdenas, E. Buñuel, J. E. Carcellera, A. Parra, J. M. Cuerva

Phys. Rev. B 2011, 83, 125424/1-125424/11.

30-“Mild Method for the Selective Esterification of Carboxylic Acids Based on the Garegg-Samuelsson Reaction”

S. P. Morcillo, L. Álvarez de Cienfuegos, A. J. Mota, J. Justicia, R. Robles

J. Org. Chem. 2011, 76, 2277-2281.

29-“Bioinspired Terpene Synthesis: a Radical Approach”

J. Justicia, L. Álvarez de Cienfuegos, A. G. Campaña, D. Miguel, V. Jakoby, A. Gänsauer, J. M. Cuerva

Chem. Soc. Rev. 2011, 40, 3525-3537.

28-“Reduction Reactions in water, supercritical CO2 and ionic liquids as green solvents”

L. Álvarez de Cienfuegos, R. Robles, D. Miguel, J. Justicia, J. M. Cuerva

Chem. Sus. Chem. 2011, 4, 1035-1048.

27-“Water-based Hydrogen-Atom Wires as Mediators in Long-Range Proton-Coupled Electron Transfer in Enzymes: a New Twist on Water Reactivity”

D. J. Cárdenas, J. M. Cuerva, M. Alías, E. Buñuel, A. G. Campaña

Chem. Eur. J. 2011, 17, 8318–8323.

26-“Organic-based Molecular Switches for Molecular Electronics”

N. Fuentes, A. Martín-Lasanta, L. Álvarez de Cienfuegos, M. Ribagorda, A. Parra, J. M. Cuerva

Nanoscale 2011, 3, 4003-4014.

25-“Ti/Pd-Promoted Intramolecular Michael-type Addition of Allylic Carboxylates to Activated Alkenes”

A. Millán, A. Martín-Lasanta, D. Miguel, L. Álvarez de Cienfuegos, J. M. Cuerva

Chem. Commun. 2011, 47, 10470-10472.

24-“Unprecedented H-Atom Transfer from Water to Ketyl Radicals mediated by Cp2TiCl”

M. Paradas, A. G. Campaña, M. L. Marcos, J. Justicia, A. Haidour, R. Robles, D. J. Cárdenas, J. E. Oltra, J. M. Cuerva

Dalton Trans., 2010, 39, 8796-8800.

23-“Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry”

M. Paradas, A. G. Campaña, T. Jiménez, R. Robles, J. E. Oltra, E. Buñuel, J. Justicia, D. J. Cárdenas, J. M. Cuerva

J. Am. Chem. Soc. 2010, 132, 12748-12756.

22-“Mn(0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of a-Deuterioalcohols”

T. Jiménez, E. Barea, J. E. Oltra, J. M. Cuerva, J. Justicia

J. Org. Chem. 2010, 75, 7022-7025.

21-“Radical Reduction of Epoxides Using a Titanocene(III)/Water System: Synthesis of β-Deuterated Alcohols and Their Use as Internal Standards in Food Analysis”

T. Jiménez, A. G. Campaña, B. Bazdi, M. Paradas, D. Arráez-Román, A. Segura-Carretero, A. Fernández-Gutiérrez, J. E. Oltra, R. Robles, J. Justicia, J. M. Cuerva Eur.

J. Org. Chem. 2010, 4288-4295.

20-“Ti-Catalyzed Barbier-type Allylations and Related Reactions”

R. E. Estévez, J. Justicia, B. Bazdi, N. Fuentes, M. Paradas, D. Choquesillo-Lazarte, J. M. García-Ruiz, R. Robles, A. Gansäuer, J. M. Cuerva, J. E. Oltra

Chem., Eur. J. 2009, 15, 2774-2791.

19-“Unexpected TiIII/Mn-Promoted Pinacol Coupling of Ketones”

M. Paradas, A. G. Campaña, R. E. Estévez, L.Älvarez de Cienfuegos, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra

J. Org. Chem. 2009, 74, 3616-3619.

18-“Efficient Propargylation of Aldehydes and Ketones Catalyzed by Titanocene(III)”

J. Justicia, I. Sancho-Sanz, E. Álvarez-Manzaneda, J. E. Oltra, J. M. Cuerva

Adv. Synth. Catal. 2009, 351, 2295-2300.

17-“Mixed Disproportionation versus Radical Trapping in Titanocene(III)-Promoted Epoxide Openings”

J. Justicia, T. Jiménez, S. P. Morcillo, J. M. Cuerva, J. E. Oltra

Tetrahedron 2009, 65, 10837-10841.

16-“Ti-Catalyzed Reformatsky-Type Coupling between -Halo Ketones and Aldehydes”

R. E. Estévez, M. Paradas, A. Millán, T. Jiménez, R. Robles, J. M. Cuerva, J. E. Oltra J.

Org. Chem. 2008, 73, 1616-1619.

15-“Titanium-Catalyzed Enantioselective Synthesis of a-Ambrinol”

J. Justicia, A. G. Campaña, B. Bazdi, R. Robles, J. M. Cuerva, J. E. Oltra

Adv. Synth. Catal. 2008, 350, 571-576.

14-“Divergent Titanium-Mediated Allylations with Modulation by Nickel or Palladium”

G. Campaña, B. Bazdi, N. Fuentes, R. Robles, J. M. Cuerva, J. E. Oltra, S. Porcel, A. M. Echavarren

Angew. Chem. Int. Ed. 2008, 47, 7515-7519.

11-“Ti-catalysed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide”

J. Justicia, L. Álvarez de Cienfuegos, R. E. Estévez, M. Paradas, A. M. Lasanta, J. L. Oller, A. Rosales, J. M. Cuerva, J. E. Oltra

Tetrahedron 2008, 64, 11938-11943.

12- “Unprecedented Hydrogen Transfer from Water to Alkenes and Alkynes Mediated by Ti(III) and Late Transition Metals”

G. Campaña, R. E. Estévez, N. Fuentes, R. Robles, J. M. Cuerva, E. Buñuel, D. Cardenas, J. E.

Oltra Org. Lett. 2007, 9, 2195-2198.

11- “Sodium Tetramethoxyborate: An Efficient Catalyst for Michael Additions of Stabilized Carbon Nucleophiles”

G. Campaña, N. Fuentes, E. Gómez-Bengoa, C. Mateo, J. E. Oltra, A. M. Echavarren, J. M. Cuerva

J. Org. Chem. 2007, 72, 8127-8130.

10- “Cp2TiCl in Natural Product Synthesis”

J. M. Cuerva, J. Justicia, J. L. Oller-López , J. E. Oltra

Top. Curr. Chem. 2006, 264, 63-91.

9- “Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by Ti(III) and Other Single-Electron-Transfer Metals?”

J. M. Cuerva, A. G. Campaña, J. Justicia, A. Rosales, J. L. Oller-López, R. Robles, D. J. Cardenas, E. Buñuel, J. E. Oltra

Angew. Chem. Int. Ed. 2006, 45, 5522-5526.

8- “Stereocontrolled Coupling between Aldehydes and Conjugated Alkenals Mediated by TiIII/H2O”

R. E. Estévez, J. L. Oller-López, R. Robles, C. R. Melgarejo, A. Gansäuer, J. M. Cuerva, J. E. Oltra

Org. Lett. 2006, 8, 5433-5436.

7- “Enantiospecific Strategy Towards Oxygen-Bridged Terpenoids: Tandem Transannular-Cyclization and Ring-Contraction Processes”

Rosales, R. E. Estévez, J. M. Cuerva, J. E. Oltra.

Angew. Chem. Int. Ed. 2005, 44, 319-322.

6- “Convenient Synthesis of Nucleosides and Isonucleoside Analogues”

L. Álvarez de Cienfuegos; A. J. Mota, R. Robles.

Org. Lett. 2005, 7, 2161-2164.

5- “Exploiting Pd(II) and Ti(III) Chemistry To Obtain g-Dioxygenated Terpenoids: Synthesis of Rostratone and Novel Approaches to Aphidicolin and Pyripyropene A”

J. Justicia, J. E. Oltra, J. M. Cuerva

J. Org. Chem. 2005, 70, 8265-8272.

4- “7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles”

J. Justicia, J. L. Oller-López, A. G. Campaña, J. E. Oltra, J. M. Cuerva, E. Buñuel, D. J. Cárdenas

J. Am. Chem. Soc. 2005, 127, 14911-14921.

3- “Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry”

J. Justicia, A. Rosales, E. Buñuel, J. L. Oller-López, M. Valdivia, A. Haïdour, J. E. Oltra, A. F. Barrero, D. J. Cardenas, J. M. Cuerva.

Chem., Eur. J. 2004, 10, 1778-1788.

2- ”General Approach to Polycyclic Meroterpenoids Based on Stille Couplings and Titanocene Catalysis”

J. Justicia, J. E. Oltra, J. M. Cuerva.

J. Org. Chem. 2004, 69, 5803-5086.

1- ”Unprecedented Barbier-type Reactions Catalysed by Titanocene(III)”

A. Rosales, J. L. Oller-López, J. Justicia, A. Gansäuer, J. E. Oltra, J. M. Cuerva

Chem. Commun. 2004, 2628-2629.